Mathematics
Q1Logic
Which one is not a logical statement:
- aIf you work hard, you will pass.
- bI am sick.
- cThe sun rises in the west.
- d30 is a number.
Answer (b): 'I am sick' has no fixed truth value because it depends on who the speaker is and when. The other three have definite truth values (even the false sun statement is a logical statement).
Revise: Algebra (Class 11 notes)
Q2Absolute value equations
If $|x-2|=5$, then $x$ is in
- a${3,5}$
- b${2,\infty}$
- c${2,5}$
- d${-3,7}$
Answer (d): $|x-2|=5$ gives $x-2=5$ or $x-2=-5$, so $x=7$ or $x=-3$.
Revise: Algebra (Class 11 notes)
Q3Set operations
$A-B=$
- a$B-A$
- b$\bar A-\bar B$
- c$\bar B-\bar A$
- d$\bar B-A$
Answer (c): $A-B=A\cap \bar B$, and $\bar B-\bar A=\bar B\cap A$, which is the same set.
Revise: Algebra (Class 11 notes)
Q4Inverse functions
If $f(x)=2x-3$, then $f^{-1}(x)=$
- a$\frac{x+3}{2}$
- b$\frac{1}{2x-3}$
- c$\frac{1}{3-2x}$
- d$\frac{1}{2x+3}$
Answer (a): Put $y=2x-3$ and solve for $x$: $x=\frac{y+3}{2}$, so $f^{-1}(x)=\frac{x+3}{2}$.
Revise: Algebra (Class 11 notes)
Q5Trigonometric functions
The period of the function $f(x)=\sin(2x+5)$ is
- a2π
- b$\pi/2$
- cπ
- d$-\pi$
Answer (c): Period of $\sin(bx+c)$ is $\frac{2\pi}{|b|}=\frac{2\pi}{2}=\pi$.
Revise: Trigonometry (Class 11 notes)
Q6Geometric progression
The fourth, seventh and tenth terms of a G.P. are $l,m,n$ respectively, then
- a$ln=m^2$
- b$l^2=m^2+n^2$
- c$l^2=mn$
- d$n^2=lm$
Answer (a): $l=ar^3$, $m=ar^6$, $n=ar^9$, so $ln=a^2r^{12}=m^2$.
Revise: Algebra (Class 11 notes)
Q7Series
The $n$th term of the series $1\cdot3+3\cdot5+5\cdot7+\cdots$ is
- a$(n+1)(n+2)$
- b$(n+1)(n+3)$
- c$4n^2-1$
- d$n(n-1)$
Answer (c): The $n$th term is $(2n-1)(2n+1)=4n^2-1$.
Revise: Algebra (Class 11 notes)
Q8Inverse trigonometric functions
The value of $\sin(\cos^{-1}x)$ is
- ax
- b$1-x^2$
- c$1+x^2$
- d$\sqrt{1-x^2}$
Answer (d): Let $\theta=\cos^{-1}x$, so $\cos\theta=x$ and $\sin\theta=\sqrt{1-x^2}$.
Revise: Trigonometry (Class 11 notes)
Q9Trigonometric equations
If $\csc^2x-2=0$, then $x$ is
- a$\pm\frac{\pi}{6}$
- b$\pm\frac{\pi}{4}$
- c$n\pi\pm\frac{\pi}{4}$
- d$n\pi+\frac{\pi}{2}$
Answer (c): $\csc^2x=2$ gives $\sin^2x=\frac12$, so $\sin x=\pm\frac{1}{\sqrt2}$ and $x=n\pi\pm\frac{\pi}{4}$.
Revise: Trigonometry (Class 11 notes)
Q10Determinants
If $A=\begin{pmatrix}k&1&0\2&0&k\0&2&-1\end{pmatrix}$ and $|A|=0$, then $k=$
- a1
- b−1
- c0
- d±1
Answer (d): Expanding along row 1: $k(0-2k)-1(-2-0)=-2k^2+2=0$, so $k^2=1$ and $k=\pm1$.
Revise: Algebra (Class 11 notes)
Q11Matrices and inverse
The value of $x$ for which $A=\begin{bmatrix}6&x-2\3&x\end{bmatrix}$ has no inverse is
- a0
- b1
- c−2
- d2
Answer (c): No inverse means $|A|=0$: $6x-3(x-2)=3x+6=0$, so $x=-2$.
Revise: Algebra (Class 11 notes)
Q12Systems of equations
If the system of equations has zero solutions only, then the solution is
- anon trivial
- btrivial
- cunique
- dparticular
Answer (b): A homogeneous system whose only solution is the zero solution has the trivial solution.
Revise: Algebra (Class 11 notes)
Q13Complex numbers
$(1+i)^6+(1-i)^6=$
- a0
- bi
- c16
- d−16
Answer (a): $(1+i)^2=2i$, so $(1+i)^6=(2i)^3=-8i$; similarly $(1-i)^6=(-2i)^3=8i$. The sum is $0$.
Revise: Algebra (Class 11 notes)
Q14Complex numbers
$\left(\frac{2i}{1+i}\right)^2=$
- a−i
- b$1+i$
- c2i
- d$-2i$
Answer (c): The square is $\frac{-4}{(1+i)^2}=\frac{-4}{2i}=\frac{-2}{i}=2i$.
Revise: Algebra (Class 11 notes)
Q15Quadratic equations
If one root of $5x^2+2x-k=0$ is the reciprocal of the other, then $k=$
- a−5
- b5
- c2/5
- d5/2
Answer (a): Product of roots $=\frac{-k}{5}=1$, so $k=-5$.
Revise: Algebra (Class 11 notes)
Q16Conic sections
The equation $x^2-2xy+y^2+3x-2=0$ represents:
- ahyperbola
- bparabola
- cellipse
- dcircle
Answer (b): Here $a=1,b=1,h=-1$, so $h^2=ab$, which is the condition for a parabola.
Revise: Analytic geometry (Class 11 notes)
Q17Area of triangle
The area of the triangle with vertices $(1,-1),(-1,1)$ and $(-1,-1)$ is
- a$\frac12$
- b−2
- c2
- d0
Answer (c): Area $=\frac12|1(1+1)+(-1)(-1+1)+(-1)(-1-1)|=\frac12(2+0+2)=2$.
Revise: Analytic geometry (Class 11 notes)
Q18Limits
$\lim_{n\to\infty}\frac{1+2+\cdots+n}{n^2}=$
- a$\frac12$
- b0
- c$1/n$
- dn
Answer (a): Sum is $\frac{n(n+1)}{2}$, so the limit is $\lim\frac{n+1}{2n}=\frac12$.
Revise: Calculus (Class 12 notes)
Q19Limits
$\lim_{x\to0}\frac{5x^2+4x\tan x}{x^2}=$
- a9
- b0
- c5
- d4
Answer (a): Divide by $x^2$: $5+4\frac{\tan x}{x}\to5+4=9$.
Revise: Calculus (Class 12 notes)
Q20Differentiation
If $y=\sqrt{x+\sqrt{x+\sqrt{x+\cdots}}}$ then $\frac{dy}{dx}=$
- a$2\sqrt x$
- b$\sqrt3x$
- c$\frac{\sqrt x}{2y-1}$
- d$\frac{1}{2y-1}$
Answer (d): Squaring, $y^2=x+y$. Differentiate: $2yy'=1+y'$, so $y'=\frac{1}{2y-1}$.
Revise: Calculus (Class 12 notes)
Q21Differentiation
If $y=e^{\sqrt{ax^2+b}}$, then $\frac{dy}{dx}=$
- a$\frac{axy}{\sqrt{ax^2+b}}$
- b$\frac{ax}{\sqrt{ax^2+b}},e^{\sqrt{ax^2+b}}$
- c$\frac{x}{\sqrt{ax^2+b}}$
- d$e^{\sqrt{ax^2+b}}$
Answer (b): By the chain rule, $y'=e^{\sqrt{ax^2+b}}\cdot\frac{2ax}{2\sqrt{ax^2+b}}=\frac{ax}{\sqrt{ax^2+b}}e^{\sqrt{ax^2+b}}$.
Revise: Calculus (Class 12 notes)
Q22Integration
$\int\frac{dx}{1-x^2}=$
- a$\cos^{-1}x+c$
- b$\frac12\ln\left|\frac{1-x}{1+x}\right|+c$
- c$\sin^{-1}x+c$
- d$\frac12\ln\left|\frac{1+x}{1-x}\right|+c$
Answer (d): Standard result: $\int\frac{dx}{1-x^2}=\frac12\ln\left|\frac{1+x}{1-x}\right|+c$.
Revise: Calculus (Class 12 notes)
Q23Definite integrals
$\int_1^2\frac{\sin(\ln t)}{t}dt=$
- a$1-\cos(\ln2)$
- b$\cos2$
- c$\cos(\ln2)$
- d$1+\cos(\ln2)$
Answer (a): Put $u=\ln t$: $\int_0^{\ln2}\sin u,du=1-\cos(\ln2)$.
Revise: Calculus (Class 12 notes)
Q24Maxima and minima
The critical points for $f(x)=x^3-3x$ are:
- a±3
- b$\pm\sqrt3$
- c±1
- d$0,\pm\sqrt3$
Answer (c): $f'(x)=3x^2-3=0$ gives $x=\pm1$.
Revise: Calculus (Class 12 notes)
Q25Area under curves
The area bounded by the x-axis and the curve $y=x^3$ and ordinates $x=2$ and $x=4$ is
- a60 sq. units
- b256 sq. units
- c240 sq. units
- d272 sq. units
Answer (a): Area $=\int_2^4x^3dx=\frac{4^4-2^4}{4}=\frac{256-16}{4}=60$.
Revise: Calculus (Class 12 notes)
English
Q26Phrasal verbs
Government has a lot to ........ road accidents.
- aanswer back
- banswer for
- canswer to
- danswer into
Answer (b): "Answer for" means to be responsible for something.
Revise: Grammar and Usage (Class 11 notes)
Q27Phrasal verbs
He inherited a fortune and ........ it in a year.
- aran into
- bran over
- cran through
- dran onto
Answer (c): 'Ran through' means used up or squandered, so he inherited a fortune and ran through it in a year.
Revise: Grammar and Usage (Class 11 notes)
Q28Phrasal verbs
His father blamed him but his mother ........ and said he had acted sensibly.
- astand for
- bstand up to
- cstand out
- dstand up for
Answer (d): 'Stand up for' means to defend or support someone, which matches the mother saying he acted sensibly.
Revise: Grammar and Usage (Class 11 notes)
Q29Phrasal verbs
Do you ........ me ........ a fool?
- atake, for
- btake, in
- ctake, to
- dtake, after
Answer (a): The phrase is 'take someone for' meaning to regard as, as in 'Do you take me for a fool?'.
Revise: Grammar and Usage (Class 11 notes)
Q30Phrasal verbs
The captain ........, not realizing that the icebergs were so close.
- aturn in
- bturn on
- cturn away
- dturn down
Answer (a): "Turned in" means went to bed, which fits the captain unaware of danger.
Revise: Grammar and Usage (Class 11 notes)
Q31Idioms
After a month's treatment at a hospital my brother is ........
- aAs good as good
- bas heavy as lead
- cAs gay as a lard
- das fit as a fiddle
Answer (d): "As fit as a fiddle" is the idiom for being in very good health.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q32Synonyms
Squeamish (similar meaning)
- avery dirty
- bgullible
- ceasily upset
- dbraggart
Answer (c): Squeamish means easily nauseated or upset.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q33Synonyms
Bramble (similar meaning)
- awild cat
- bwild bush with thorn
- ctall plant
- dwild animal
Answer (b): A bramble is a prickly, thorny wild shrub such as the blackberry bush.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q34Synonyms
Congruous (similar meaning)
- aconsistent
- bcovert
- cIrregular
- dclamorous
Answer (a): Congruous means in agreement or harmony, i.e. consistent.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q35Antonyms
Savior (opposite meaning)
- aProtector
- bdestroyer
- cNurturer
- ddesigner
Answer (b): A savior rescues; the opposite is a destroyer.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q36Antonyms
Scabrous (opposite meaning)
- ascaly
- bscabby
- cdecent
- dzigzag
Answer (c): Scabrous means rough or indecent; its opposite among the options is decent.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q37Antonyms
Un-availing (opposite meaning)
- aUnavailable
- bre past
- cSuccessful
- drare
Answer (c): Unavailing means ineffective or unsuccessful, so the opposite is successful.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q38Prepositions
He died ........ cancer but she died ........ a train accident.
- aout, at
- boff, by
- cfor, in
- dof, in
Answer (d): We say 'died of cancer' for the disease and 'died in a train accident' for the accident.
Revise: Grammar and Usage (Class 11 notes)
Q39Prepositions
Divide forty ........ eight but divide these apples ........ the two children.
- afor, among
- bat, between
- cin, among
- dby, between
Answer (d): We divide a number 'by' another and share things 'between' two people.
Revise: Grammar and Usage (Class 11 notes)
Q40Prepositions
It is a lovely place to live ........
- ain
- bfor
- cfor, in
- dof, in
Answer (a): The infinitive "to live" takes the preposition "in" at the end.
Revise: Grammar and Usage (Class 11 notes)
Q41Prepositions
He is angry ........ and indifferent ........ me.
- afrom, from
- bby, by
- cwith, to
- dduring
Answer (c): The correct collocations are "angry with" and "indifferent to".
Revise: Grammar and Usage (Class 11 notes)
Q42Prepositions
You alone can relieve me ........ this anxiety.
- afrom
- bof
- cin
- dduring
Answer (a): "Relieve someone from" a worry is the usual form.
Revise: Grammar and Usage (Class 11 notes)
Q43Conjunctions
He took the food. Play with your watch ........ he breaks it.
- ashould
- bin case
- clest
- dmight
Answer (c): "Lest" introduces a feared result and fits the warning.
Revise: Grammar and Usage (Class 11 notes)
Q44Idioms
On the bottle
- ateetotaler
- bvegetarian
- cdrinking a lot
- davoid alcohol
Answer (c): "On the bottle" means drinking heavily.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q45Idioms
On the rocks
- ain great success
- bin serious trouble
- cheavy star
- din progress
Answer (b): "On the rocks" means in difficulty or close to failure.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q46Idioms
Call it a night
- astop some activity
- bfeel lazy
- cenjoy the night
- dbelated activity
Answer (a): It means to stop what you are doing for the night.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q48Idioms
Over the hill
- ahigh land
- bmountain area
- cmost difficult part
- drough road
Answer (c): 'Over the hill' can mean past the hardest or worst part, which fits option c best among the choices.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q49Word structure
How many syllables does the word "pleasurable" have?
- aThree
- btwo
- cone
- dfour
Answer (d): plea-sur-a-ble has four syllables.
Revise: Vocabulary and Word Formation (Class 11 notes)
Q50Vocabulary
The fear of blood is called
- achirophobia
- bergophobia
- cmonomania
- dhematophobia
Answer (d): Hematophobia is the fear of blood.
Revise: Vocabulary and Word Formation (Class 11 notes)
Physics
Q51Dimensions
In the gas equation $\left(p+\frac{a}{V^2}\right)(V-b)=RT$, the dimensions of 'a' are
- a$ML^2T^{-2}$
- b$ML^5T^{-2}$
- c$L^6$
- d$L^{-6}$
Answer (b): $a/V^2$ has the dimensions of pressure, so $[a]=[p][V^2]=ML^{-1}T^{-2}\cdot L^6=ML^5T^{-2}$.
Revise: Physical Quantities (Class 11 notes)
Q52Significant figures
The number of significant figures in 1400 are
- a0
- b1
- c2
- d4
Answer (c): Trailing zeros without a decimal point are not significant, so only 1 and 4 count: 2.
Revise: Physical Quantities (Class 11 notes)
Q53Displacement
A man walks 8 m forwards East and 6 m towards North. The magnitude of displacement is
- a14 m
- b2 m
- c8 m
- d$\sqrt{8^2+6^2}$ m
Answer (d): The two legs are perpendicular, so displacement is $\sqrt{8^2+6^2}=10$ m.
Revise: Vectors (Class 11 notes)
Q54Projectile motion
If initial velocity of a projectile is doubled, the maximum range will be
- a2 times
- b4 times
- c8 times
- d16 times
Answer (b): Range $R=\frac{u^2\sin2\theta}{g}\propto u^2$, so doubling $u$ makes it 4 times.
Revise: Kinematics (Class 11 notes)
Q55Friction
Which of the following friction is maximum?
- arolling
- bkinetic
- crolling + kinetic
- dstatic
Answer (d): Limiting static friction is greater than kinetic and rolling friction.
Revise: Dynamics (Class 11 notes)
Q56Variation of g
If the speed of rotation of earth increases, the weight of the body on earth's surface becomes
- asmaller
- bzero
- cgreater
- dunaffected
Answer (a): Effective $g'=g-\omega^2R\cos^2\lambda$ falls as $\omega$ rises, so weight decreases.
Revise: Gravitation (Class 11 notes)
Q57Buoyancy
A weightless rubber balloon has 100 g of water in it. Its weight in water will be
- a100 g
- b50 g
- c> 100 g
- dzero
Answer (d): The balloon displaces its own weight of water, so buoyancy cancels weight and apparent weight is zero.
Revise: Fluid Statics (Class 12 notes)
Q58Temperature scales
The temperature of a substance increases by $270^\circ$C. This increase is equal to
- a300 K
- b0 K
- c270 K
- d273 K
Answer (c): A change of 1 degree C equals a change of 1 K, so an increase of 270 C is an increase of 270 K.
Revise: Heat and Temperature (Class 11 notes)
Q59Kinetic theory
Which of the following gases possess maximum rms speed at a given temperature?
- a$H_2$
- b$N_2$
- c$O_2$
- dHe
Answer (a): $v_{rms}=\sqrt{3RT/M}$ is largest for the smallest molar mass; $H_2$ has $M=2$.
Revise: Ideal Gas (Class 11 notes)
Q60Black body radiation
The black body emits
- aline spectrum
- bband spectrum
- ccontinuous spectrum
- dmixed spectrum
Answer (c): Black body radiation covers all wavelengths, a continuous spectrum.
Revise: Quantization of Energy (Class 12 notes)
Q61Curved mirrors
The field of view is maximum for
- aplane mirror
- bconcave mirror
- cconvex mirror
- dcylindrical mirror
Answer (c): A convex mirror forms a diminished virtual image and gives the widest field of view.
Revise: Reflection at Curved Mirrors (Class 11 notes)
Q62Scattering of light
Sky seen from earth appears blue because of
- ascattering of lights
- bdispersion of lights
- creflection
- dpolarization
Answer (a): Short wavelengths scatter more (Rayleigh scattering), so blue light reaches us from all directions.
Revise: Dispersion (Class 11 notes)
Q63Defects of vision
A person cannot see objects clearly beyond 50 cm. The power of the lens to correct the vision is
- a+5 D
- b-5 D
- c-0.5 D
- d-2 D
Answer (d): Needed lens is concave with $f=-0.5$ m, so $P=\frac{1}{f}=-2$ D.
Revise: Lenses (Class 11 notes)
Q64Electric charge
An isolated conducting sphere is given a positive charge. Its mass
- aincreases
- bdecreases
- cremains constant
- dmay increase or decrease depending on material
Answer (b): Positive charging means electrons are removed, so the mass decreases slightly.
Revise: Electric Charges (Class 11 notes)
Q65Capacitor combinations
Three capacitors each of capacitance 3 $\mu$F are connected in series. The net capacitance is
- a1 μF
- b(1/3) μF
- c3 μF
- d9 μF
Answer (a): $\frac1C=\frac13+\frac13+\frac13=1$, so $C=1,\mu$F.
Revise: Capacitor (Class 11 notes)
Q66Kirchhoff's laws
Kirchhoff's voltage law is based on the principle of conservation of
- acharge
- benergy
- cmomentum
- dmass of charges
Answer (b): The loop rule states that the net energy gained per unit charge around a loop is zero.
Revise: DC Circuit (Class 11 notes)
Q67Motion in magnetic field
A charged particle enters in a strong magnetic field. Then its kinetic energy
- aincreases
- bdecreases
- cremains constant
- dincreases and becomes constant
Answer (c): The magnetic force is perpendicular to velocity and does no work, so kinetic energy is constant.
Revise: Magnetic Field (Class 12 notes)
Q68Inductance
The self-inductance of a straight wire is
- azero
- b∞
- cnegative
- dpositive
Answer (a): A straight wire has no loop and links no flux with itself, so its self-inductance is taken as zero.
Revise: Electromagnetic Induction (Class 12 notes)
Q69Photoelectric effect
The photoelectric effect is based on the law of conservation of
- aenergy
- bmass
- cmomentum
- dangular momentum of photons
Answer (a): Einstein's equation $h\nu=\phi+K_{max}$ expresses energy conservation.
Revise: Photons (Class 12 notes)
Q70Radioactivity
When a radioactive element emits a $\beta$-particle the mass number of the atom
- aincrease by one
- bdecreases by one
- cremains the same
- ddecreases by four
Answer (c): In beta decay a neutron becomes a proton, so the atomic number rises by 1 while the mass number is unchanged.
Revise: Radioactivity and Nuclear Reaction (Class 12 notes)
Q71p-n junction diode
On increasing the reverse bias to a large value in a p-n junction diode, the current
- aincreases slowly
- bremains fixed
- cdecreases slowly
- dsuddenly increases
Answer (d): At the breakdown voltage the reverse current rises sharply.
Revise: Semiconductor Devices (Class 12 notes)
Q72Wave equation
The equation of sound wave is $y=0.0015\sin(62.4x+316t)$. The wave length of sound wave is
- a0.2 unit
- b0.1 unit
- c3.3 unit
- dnot known from the given equation
Answer (b): Wave number $k=62.4$, so $\lambda=\frac{2\pi}{k}=\frac{6.283}{62.4}\approx0.1$ unit.
Revise: Wave Motion (Class 12 notes)
Q73Reflection of waves
A wave is reflected from a rigid support. The change of phase on reflection will be
- a0
- b$\pi/2$
- c$\pi/4$
- dπ
Answer (d): Reflection at a rigid (denser) boundary inverts the wave, a phase change of $\pi$.
Revise: Mechanical Waves (Class 12 notes)
Q74Doppler effect
A car at rest is playing 'HORN'. If it starts moving towards you, the pitch heard would be
- ahigher
- bless
- csame
- dnil
Answer (a): A source moving toward the observer raises the apparent frequency (Doppler effect), so the pitch is higher.
Revise: Acoustic Phenomena (Class 12 notes)
Q75Hydrogen spectrum
In which region of electromagnetic spectrum does the Lyman series of H atom lie?
- aUltraviolet
- bvisible
- cinfrared
- dmicrowave
Answer (a): Lyman series ends on $n=1$ and gives wavelengths of about 91 to 122 nm, in the ultraviolet.
Revise: Quantization of Energy (Class 12 notes)
Chemistry
Q76Oxidation number
The oxidation of Fe in $K_3[Fe(CN)_6]$ is
- a+2
- b+3
- c+4
- d+5
Answer (b): $3(+1)+x+6(-1)=0$ gives $x=+3$.
Revise: Oxidation and Reduction (Class 11 notes)
Q77Mole concept
How many oxygen atoms are present in 8.0 g of oxygen?
- a$6.023\times10^{23}$
- b$3.0115\times10^{23}$
- c$7.83\times10^{23}$
- d$5.83\times10^{23}$
Answer (b): 8 g of O is $\frac{8}{16}=0.5$ mol of atoms, so $0.5\times6.023\times10^{23}=3.0115\times10^{23}$.
Revise: Stoichiometry (Class 11 notes)
Q78Electronic configuration
"Atomic orbitals are filled up in the ground state in order of increasing energy level". This statement is called
- aPauli's Exclusion Principle
- bHund's rule
- cAufbau principle
- dHeisenberg's Uncertainty Principle
Answer (c): Filling orbitals in order of increasing energy is the Aufbau principle.
Revise: Atomic Structure (Class 11 notes)
Q79Hydrogen spectrum
The spectral region for the Lyman series of hydrogen spectrum lies in the
- ainfrared region
- bvisible region
- cultra-violet region
- dmicrowave region
Answer (c): Lyman lines come from transitions to $n=1$ and lie in the ultraviolet.
Revise: Atomic Structure (Class 11 notes)
Q80Crystal structure
The crystal structure of sodium chloride is
- abody centered cubic
- bsimple cubic
- chexagonal
- dface centered cubic
Answer (d): NaCl has Cl$^-$ ions in a fcc lattice with Na$^+$ in the octahedral holes.
Revise: States of Matter (Class 11 notes)
Q81Periodic properties
Which of the following halogens has highest electron affinity?
- afluorine
- biodine
- cbromine
- dchlorine
Answer (d): Chlorine has the highest electron affinity; fluorine's is lower because of small size and electron repulsion.
Revise: Classification of Elements (Class 11 notes)
Q82Industrial chemistry
Ammonia is manufactured by
- aHaber's process
- bContact process
- cDown's process
- dOstwald's process
Answer (a): $\ce{N2 + 3H2 <=> 2NH3}$ is the Haber process.
Revise: Chemistry of Non-Metals (Class 11 notes)
Q83Oxides
An example of acidic oxide is
- a$SO_2$
- b$N_2O$
- cCO
- dZnO
Answer (a): $\ce{SO2}$ reacts with water to give an acid and is an acidic oxide; $\ce{N2O}$ and CO are neutral and ZnO is amphoteric.
Revise: Chemistry of Non-Metals (Class 11 notes)
Q84VSEPR theory
The shape of $BeF_2$ molecule on the bases of VSEPR theory is:
- atrigonal planar
- blinear
- ctetrahedral
- dtrigonal pyramidal
Answer (b): Be has two bond pairs and no lone pair, giving a linear molecule.
Revise: Chemical Bonding (Class 11 notes)
Q85Volumetric analysis
Which of the following compound is not a primary standard substance?
- aoxalic acid
- bpotassium dichromate
- cpotassium bromated
- dpotassium permanganate
Answer (d): Potassium permanganate is not a primary standard because it is not stable and is hard to obtain pure. Oxalic acid, potassium dichromate and potassium bromate are primary standards (option c is a misspelling of bromate).
Revise: Volumetric Analysis (Class 12 notes)
Q86Acids and bases
An example of Lewis base is
- a$BF_3$
- b$SnCl_4$
- c$FeCl_3$
- d$NH_3$
Answer (d): $\ce{NH3}$ has a lone pair to donate; the others are electron-deficient Lewis acids.
Revise: Ionic Equilibrium (Class 12 notes)
Q87Electrochemistry
The unit of equivalent conductivity is
- a$Scm^2,equivalent^{-1}$
- b$Ohm.cm$
- c$S,cm^{-1}$
- d$S,cm^2,mole^{-1}$
Answer (a): Equivalent conductivity is $\Lambda_{eq}=\kappa\times1000/N$, with units $S,cm^2,equivalent^{-1}$. The mole unit applies to molar conductivity.
Revise: Electrochemistry (Class 12 notes)
Q88Units of energy
1 calorie is equals to
- a4.184 Joules
- b5.174 Joules
- c6.184 Joules
- d3.184 Joules
Answer (a): By definition, 1 cal $=4.184$ J.
Revise: Chemical Thermodynamic (Class 12 notes)
Q89Thermodynamics
Gibb's Helmholtz equation is
- a$\Delta E=Q+W$
- b$\Delta G=\Delta H-T\Delta S$
- c$G=H+TS$
- d$\Delta E=Q-W$
Answer (b): The Gibbs-Helmholtz relation is $\Delta G=\Delta H-T\Delta S$.
Revise: Chemical Thermodynamic (Class 12 notes)
Q90Chemical kinetics
The unit of rate constant for third order reaction is
- a$S^{-1}$
- b$mol^{-2}L^2s^{-1}$
- c$mol,L s^{-1}$
- d$mol,L^{-1}s^{-1}$
Answer (b): $k$ has unit $(\text{mol L}^{-1})^{1-n},\text{s}^{-1}$; for $n=3$ this is $\text{mol}^{-2}\text{L}^2\text{s}^{-1}$.
Revise: Chemical Kinetics (Class 12 notes)
Q91Aromatic hydrocarbons
The reaction of benzene with alkyl chloride in presence of anhydrous AlCl3 is
- aFriedel Craft's reaction
- bWurtz's reaction
- cReimer Tiemann's reaction
- dGrignard reaction
Answer (a): Alkylation of benzene with an alkyl halide and $\ce{AlCl3}$ is the Friedel-Crafts reaction.
Revise: Aromatic Hydrocarbons (Class 11 notes)
Q92Alcohols
Primary, secondary and tertiary alcohols are distinguished by
- aVictor Meyer's test
- bTollen's reagent
- cHoffman's test
- dBeilstein's test
Answer (a): Victor Meyer's test gives different colours (red, blue, colourless) for 1°, 2° and 3° alcohols.
Revise: Alcohols (Class 12 notes)
Q93Ethers
Williamson's synthesis is used for the preparation of
- aalcohol
- baldehyde
- cketone
- dether
Answer (d): $\ce{R-ONa + R'-X -> R-O-R'}$ gives ethers.
Revise: Ethers (Class 12 notes)
Q94Aldehydes
The catalyst used in Rosenmund's reduction is
- a$Pd-CuSO_4$
- b$Pd-CaSO_4$
- c$Pd-CuCl_2$
- d$Pd-BaSO_4$
Answer (d): Rosenmund reduction of acid chlorides to aldehydes uses Pd on $\ce{BaSO4}$ (poisoned with quinoline).
Revise: Aldehydes and Ketones (Class 12 notes)
Q95Phenols
The reaction of Phenol with concentrated nitric acid and concentrated sulphuric acid gives:
- apicric acid
- b2 - nitro phenol
- c4-nitrophenol
- daniline
Answer (a): Conc. $\ce{HNO3}$ with $\ce{H2SO4}$ nitrates phenol fully to 2,4,6-trinitrophenol (picric acid).
Revise: Phenols (Class 12 notes)
Q96Amines
When benzamide is treated with aqueous $Br_2$ in presence of aqueous alkali, the product formed is:
- aaniline
- bbenzene
- ctoluene
- dnitroso amine
Answer (a): This is Hofmann bromamide degradation: $\ce{C6H5CONH2 -> C6H5NH2}$.
Revise: Amines (Class 12 notes)
Q97Biomolecules
Amino acid contains
- a- OH group
- b- CHO group
- c
- d-CO group
Answer (c): Amino acids carry both an amino group $-NH_2$ and a carboxyl group $-COOH$.
Revise: Amines (Class 12 notes)
Q98Dyes
Martius yellow is an example of
- adirect dyes
- bacid dyes
- cbasic dyes
- dmordant dyes
Answer (b): Martius yellow (a nitro naphthol dye) is classed as an acid dye.
Q99Salts
The molecular formula of green vitriol is
- a$FeCl_3$
- b$FeSO_4.7H_2O$
- c$ZnSO_4.7H_2O$
- d$CuSO_4.5H_2O$
Answer (b): Green vitriol is hydrated ferrous sulphate, $\ce{FeSO4.7H2O}$.
Revise: Transition Metals (Class 12 notes)
Q100Metallurgy
Which is the most important ore of Zinc
- aZincite
- bZinc blende
- cFramklinite
- dWilemite
Answer (b): Zinc blende (ZnS, sphalerite) is the chief ore of zinc.
Revise: Chemistry of Metals (Class 11 notes)